Showing posts with label evaporation. Show all posts
Showing posts with label evaporation. Show all posts

Wednesday, 27 February 2013

"Bio-engineering" scientist hasn't a clue what he's talking about.

On the Green blog on the NY Times website , if you're interested, I just read Nature, Re-engineered to Meet Energy Needs.
Thousands of inventors, engineers and entrepreneurs gathered in a suburban Washington convention center on Monday for the annual three-day meeting of ARPA-E, the Advanced Research Projects Agency – Energy. It wasn’t quite the Oscars. At the registration desk, attendees received a goody bag that included a report on clean energy from the Pew Charitable Trusts and a refrigerator magnet that showed the periodic table of the elements.
Judging by what follows in the article, the goody bags should have included copies of "Metal Refining for Dummies", "Photosynthesis for Dummies" and "Greenhouse Gas Absorption for Dummies", and you'll soon learn why.
But the breakout sessions held true to ARPA-E’s tradition: there were lots of swing-for-the-fence ideas. These included finding a high-efficiency, low-cost way to turn surplus natural gas into liquid fuel for cars and trucks, and identifying something to burn other than hydrocarbons so that carbon dioxide is not one of the byproducts.
One researcher proposed burning aluminum instead. One challenge is that the “ashes,” or oxidized metal, would be hard to recycle back into aluminum without big releases of carbon dioxide.
That's a great combo - use natural gas, a hydrocarbon, as fuel for vehicles (it's already being done and is being refined), while at the same time "identifying something to burn other than hydrocarbons". That's just priceless. Even more priceless is the idea of burning aluminium, which uses (in comparison with other metals) a vast amount of electricity in the refining process. Turning the oxide back into aluminium would likely use even more. All this to achieve what? Getting a bit of heat out of it, at a vastly lower efficiency than in the refining process. It'd be much cheaper (and easier) to burn the dollar bills and sequester the CO2, but I've just had a brilliant idea - use just a little of the electricity instead of burning the aluminium. I'm not just a pretty face, you know,

Talking of CO2, there's a scientist who doesn't appear to know much about its effects on plants. In fact he doesn't appear to know much at all.
One particularly ambitious idea presented on Monday was to re-engineer plants so that their leaves reflect rather than absorb more light. In an age of global climate change, with shifting rainfall patterns, changing reflectivity holds appeal. The technology would save water, which means saving energy because the water that the plants need often must be pumped. It could prove a way to help crops grow with less rainfall. 
Some of those crops can be used to produce energy as well. And increasing the amount of light that bounces back into space would help to limit global warming.
The notion is that crops will absorb light in the visible spectrum yet reflect some of the infrared and ultraviolet light, which heats the leaves. “Plants have a maximum efficiency of about 6 percent,’’ said Robert Conrado, an agency scientist. And plants regulate their temperature much the way people do, by giving off water, which cools as it evaporates. “All energy that is not able to be captured is dissipated as heat,’’ he said. “And that’s a lot of water.’’
In a hot climate, a cornfield can give off the equivalent of eight inches of rainfall in a month, he said, and agricultural irrigation accounts for 81 percent of water use in this country. The proportion is even higher in poorer places, which have fewer dishwashers and washing machines.
And some of that energy would radiate back into space, reducing global warming, Dr. Conrado said.Whether butterfly wings or fruits, he said, “nature has already evolved mechanisms for tailored light reflection.”
Re-engineer plants so that the leaves reflect some of the infrared and ultraviolet? Pull out the copy of "Photosynthesis for Dummies" and turn to the page which explains that plant leaves absorb UV in photosynthesis. As far as plants and UV are concerned, more UV is better. Remind yourself that a number of studies have shown conclusively that higher levels of CO2 reduce the time that plant stomata (pores) are open, thus reducing evapotranspiration, which means that plants loose less water to the atmosphere.

Pull out the copy of "Greenhouse Gas Absorption for Dummies" which explains that most of the shortwave infrared from the Sun is absorbed by water vapour in the atmosphere, and not much reaches the surface, so re-engineering plants to reflect some of that "not much" will have little effect. Remind yourself that most, if not all of that reflected infrared will be also absorbed by water vapour, and not that far above the surface either. Remind yourself that a short while ago, other scientists were pointing out that infrared absorbed by off-the-ground vegetation (trees to you and me) absorbed infrared and kept the ground below cool whereas grassland tended to reflect it and warm the atmosphere immediately above when it was absorbed by water vapour. Not a good thing as they saw it, just an interesting fact as I saw it.

Dr. Conrado should peruse both volumes and read a few more published  abstracts on topics he ought to know more about. For the final words, back to the article
So far the agency has invested $770 million in 285 projects, “and we’re proud of every single one of them,’’ said Cheryl Martin, the agency’s deputy director, in opening remarks to several thousand attendees. Although most will never be commercialized, the strikeouts are not as important as the home runs.
Most will never be commercialized because, judging on present evidence, most don't work, can't work, or if they do work, have negative cost benefits (if they actually have any benefits at all). Perhaps the "home runs" will also turn out to be "own goals". Crazy people with crazy ideas who can't see beyond the top row of their keyboards. Even idiots have the right ideas some of the time.

Wednesday, 8 February 2012

Bill McKibben - 100% wetter than he was forty years ago

I generally pay little attention to Bill McKibben's seemingly daily rants; however, he seems to have excelled himself in pseudo-facts and self-contradictory logic in the last couple of days. Mckibben was invited to testify before the House Natural Resources and Energy Committee in Vermont on Tuesday (7th. Feb. 2012). Among his many exaggerated and unsubstantiated claims outlined here was this gem:
From the beginning to the end of his testimony, McKibben voiced his frustration with the lack of action out of Washington DC, capital of the country that historically has contributed one third of the greenhouse gases now in the atmosphere.
Really? Silly me thought it was around one third of what was emitted into the atmosphere. Bill seems to have difficulty getting his (huge) head around even the basics. After his usual stuff about "climate deterioration"  and the wonderful "Everything frozen on earth is melting" (did you shut the freezer door dear?) comes this:
“Most remarkable, and certainly for Vermont most dangerous, are changes in hydrology. Warm air holds more water vapor than cold. What that means is that with this one-degree increase in temperature [that has occurred so far], the atmosphere is about 4% wetter than it was forty years ago. That is a staggeringly large change in a basic physical parameter, one that we assume has held basically steady for ten thousand years. What it does is load the dice for two things: drought and flood. We get more evaporation in arid areas. The flip side of this is that once that water vapor has evaporated into the atmosphere, it’s going to come down. This means that we load the dice again for deluge and downpour and flood, and we have seen it all over the world.”
Magic stuff, water - it can be in two places at once, both in the atmosphere as increased water vapour, and falling as rain. I really like that "one that we assume has held basically steady for ten thousand years" bit - who is "we", and how would "we" know that? "We get more evaporation in arid areas" - let's see, water vapour content in the air rises, which means that more evaporates from the ground in "arid" areas? I think he must mean less - it's "settled science", Bill.

"The flip side of this is that once that water vapor has evaporated into the atmosphere, it’s going to come down" - see? Two places at once - told you so. "This means that we load the dice again for deluge and downpour and flood, and we have seen it all over the world" - does that include your "arid areas" Bill? Of course that extra water vapour has to form clouds (which are water droplets, not vapour) before it becomes "deluge and downpour and flood", so it must be in three places at once. There must have been a significant corresponding increase in cloud, then, eh Bill? Even Wikipedia reckons that's where rain comes from. The only increase in cloudiness is in Bill's brain.

Just a mo - Bill also witters on elsewhere about feet or yards or metres (or was it tens of those units? I forget- I need to forget) of sea level rise "in the pipeline". The XL pipeline, is it Bill? (Sorry -couldn't resist that little dig. Bill is resisting the big dig). Where does that "4% wetter" come from - someone leave the tap on? (Note my kitchen theme today - I'm warming to it) I read somewhere once, could have been the back of a cereal packet (he won't leave the kitchen out of it - Ed.) that the oceans covered a bit more than two-thirds of the Earth's surface, and were the source of most of the water in the atmosphere. Oh - I forgot Bill's "arid areas". Must be a lot of water in them "arid areas" to affect rainfall in the "non-arid areas".

Sorry - I've lost the thread - I found myself thinking of a foaming pint in a cosy hostelry with a real "killer-coal" fire not ten minutes walk away. That barmaid, the one with the tight black skirt... I  never get a cloudy pint from her. Ahem! Back to the kitchen once more. Where was I - oh yes - the source of all that "extra" water must be the oceans (don't forget the "arid areas" - Ed.). So there must be less water in the oceans, right? No - on 350,org Bill says that "Sea levels have begun to rise, and scientists warn that they could go up as much as several meters this century". "Begun to rise" - I should do some research, and find out when that "begun" began. I could even make it my special subject - who knows - even start a blog with graphs and stuff!

UPDATE 8th Feb 2012 2310

Just in from the scientific literture, and not from the "Gospel according to Bill McKibben":

Surface Water Vapor Pressure and Temperature Trends in North America during 1948-2010
V. Isaac and W. A. van Wijngaarden
Journal of Climate 2012

Abstract:
Over 1/4 billion hourly values of temperature and relative humidity observed at 309 stations located across North America during 1948-2010 were studied. The water vapor pressure was determined and seasonal averages were computed. Data were first examined for inhomogeneities using a statistical test to determine whether the data was fit better to a straight line or a straight line plus an abrupt step which may arise from changes in instruments and/or procedure. Trends were then found for data not having discontinuities. Statistically significant warming trends affecting the Midwestern U.S., Canadian prairies and the western Arctic are evident in winter and to a lesser extent in spring while statistically significant increases in water vapor pressure occur primarily in summer for some stations in the eastern half of the U.S. The temperature (water vapor pressure) trends averaged over all stations were 0.30 (0.07), 0.24 (0.06), 0.13 (0.11), 0.11 (0.07) C/decade (hPa/decade) in the winter, spring, summer and autumn seasons, respectively. The averages of these seasonal trends are 0.20 C/decade and 0.07 hPa/decade which correspond to a specific humidity increase of 0.04 g/kg per decade and a relative humidity reduction of 0.5%/decade.
A "specific humidity increase of 0.04 g/kg per decade" - that's 40 milligrams per kilogram or 0.004% per decade. Those "arid areas" are sure giving up their water fast.

Saturday, 25 June 2011

A Question of Scale (3) - Latent Heat

Latent (hidden) heat plays an important role in climate and weather, but its importance is often overlooked or misunderstood. Heat is simply the energy of vibration of atoms or molecules in solids, liquids and gases. Heat is motion; motion is heat. More motion equals more heat - hotter. Less motion equals less heat - colder.

In a solid such as ice, water molecules are fixed relative to one another. They can move a small amount relative to their neighbours, but can't move freely through the solid; it's as if they were inter-connected by springs or stiff elastic. These notional "springs" are the strong attractive force which operates at the relatively short distance between the molecules.

In a liquid, molecules vibrate much more, and are free to move about, like table-tennis balls in a bucket. Shake the bucket, and the balls move about. Shake it more; balls from the bottom can move to the top, and vice-versa. They collide with one another, thus transferring energy of motion (kinetic energy). More vigorous shaking may result in a ball leaping above the others - it may even leap out of the bucket. This is a simple illustration of evaporation - balls moving through the air have effectively become a gas.

In a gas, the molecules have much greater energy of motion, and are free to move in all directions like the balls that escaped from the bucket. They collide one with another, transferring and sharing their kinetic energy. As a consequence they are much farther apart than molecules in a liquid or solid.

To transform a solid into a liquid, enough heat has to be added for the kinetic energy of the atoms or molecules to overcome the strong attraction between them. The amount of heat per unit of mass of the solid is termed the latent heat of fusion for that solid. It is many times greater than the specific heat, which is the amount of heat per unit of mass to raise its temperature by one degree Celsius (or Kelvin). Why is this important? It takes far more heat to melt ice than it does to warm ice to its melting point.

The specific heat of ice is 2.108 kJ/kgK (thousand joules per kilogram per degree Kelvin); the latent heat of fusion of ice is 334 kJ/kg. It takes 158 times as much heat to melt a given mass of ice as to raise its temperature by one degree. It appears to me that it's a common misconception that once ice is raised to its melting point it will melt rapidly. It would take 158 times longer to melt ice than to raise its temperature the last degree to the melting point, given the same rate of heat input.

We use this property of ice almost daily. A couple of ice cubes in a glass of juice or spirit lowers the temperature rapidly, but that cooling reduces the heat available for the ice to melt, which must then come from the surroundings - the sun, the air or a warm hand. A large ice-floe or iceberg can drift for months before disappearing completely. Some of the much larger ones can endure for years. The ice that does melt removes a lot of heat from the surrounding air and water, reducing the temperature difference and slowing the transfer of heat and therefore the melting rate.

Enough about ice - I can see the bottom of my glass. Conversion of a liquid into a gas, as in water to water vapour (or steam) requires an even greater input of heat energy as does melting. The figure of 334 kJ/kg for ice to water compares with 2,270 kJ/kg for water to vapour - nearly 7 times as much. This is important because it's the mechanism by which vast quantities of heat energy are transported aloft from the surface of the Earth into the atmosphere. It's a major factor in climate - some would argue (including myself) that it's the major factor.

Evaporation of water cools land and more importantly ocean surfaces, the resulting upward convection drives surface winds, and the water vapour condenses to forms clouds which block sunlight from reaching the surface. The condensation into clouds releases the latent heat into the upper atmosphere, where it's better placed to finally radiate into space and balance the incoming dynamo of the climate; energy from the sun. Water and its latent heat therefore has a major impact in cooling the Earth's surface, a direct result of its unusual properties compared with other common substances.

See this page for the properties of dihydrogen monoxide (or hydroxyl acid - it's nasty stuff, thousands of people die because of it, or a lack of it, or in it, every year).